Firstaid measures general advice if symptoms persist, call a physician. P202 do not handle until all safety precautions have been read and understood. A system of local andor general exhaust is recommended to keep employee exposures as low as possible. Straight streams of water fire fighting fire fighting instructions.
Possibility of hazardous reactions can ignite spontaneously in contact with air. Often reactive with water to generate toxic or flammable gases. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Ethylaluminum dichloride is one of numerous organometallic compounds sold by american elements under the trade name ae organometallics for uses requiring nonaqueous solubility such as recent solar energy and water treatment applications. Methods and material for containment and cleaning up spills should be contained, solidified, and placed in suitable containers for disposal. Organometallics, such as ethyl aluminum dichloride, are reactive with many other groups.
Toluene is classified as dangerous goods according to the australian code for the transport of dangerous goods by road and rail. This product is not known to contain any components at 0. Diethylaluminum ethoxide dealox diethylaluminum ethoxide dealox is a pyrophoric liquid supplied undiluted or as a solution in a compatible hydrocarbon solvent. Identification of substance mixture and of supplier product identifier. Safety data sheet according to federal register vol. Page 3 of 16 msds toluene dioxide co2 to extinguish flames. Although the predominant use of alkylaluminum halides is as. Each manufacturing facility should have a thorough training program for employees and appropriate work processes, ventilation, and safety equipment in place to limit exposure. You need to choose a quantity before adding items to cart. If inhaled if breathed in, move person into fresh air. Ethylaluminum dichloride is used as a catalyst component in the polyolefin industry, for the synthesis of synthetic rubbers and for the dimerisation of olefins.
Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Safety data sheet northwest missouri state university. Moving container to a warm location should melt the solid. Toluene reacts vigorously with allyl chloride or other alkyl halides even at 70 c in the presence of ethyl aluminum dichloride or ethyl aluminum sesquichloride. Ethylaluminum dichloride eadc is a zieglernatta catalyst used for the manufacture of high density and linear low density polyethylene and refinery isomerization processes dimersol. The solvent, toluene affects liver and kidney function. Although kidney toxicity has not been common in cases of occupational toluene exposure, there has been at least one report of renal toxicity following a 40year occupational toluene exposure. Cc persons exposed only to toluene vapor do not pose substantial risks of secondary. Toluene c6h5ch3 or c7h8 cid 1140 structure, chemical names, physical and chemical properties. Our msds database is an easy to use, do it yourself tool, and best of all. Angled septuminlet adapter z118206 or straight septuminlet adapter, 6mm i. Some test results have shown that toluene was teratogenic in the absence of maternal toxicity, but the applicability of these results to whmis is unknown. There are no known chronic effects related to this compound.
Specific target organ toxicity after repeated exposure category 2. Acroseal glass bottle ethylaluminium dichloride, 1. Toluene does not cause the severe injury to the bone marrow that is characteristic of benzene poisoning. Safety data sheet paratoluene sulfonic acid date prepared. It is also employed as a catalyst for friedelcrafts acylations. Chemical stability stable in sealed containers stored under a dry inert atmosphere. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. Identification of the substancemixture and of the companyundertaking 1. No warranty, express or implied, is made and labchem inc. Safety data sheet according to 29cfr19101200 and ghs rev.
Risk phrases safety phrases r11 highly flammable r22 harmful if swallowed r3638 irritating to the eyes and skin r63 possible risk of health to unborn child r67 vapours may cause drowsiness s36 wear suitable clothing. The warm liquid may be transferred using syringe techniques. Toluene 108883 4050% naphtha petroleum, heavy alkylate 64741657 4050% appears in section 3 of title iii of the superfund amendment reauthorization act sara of 1986 and 40 cfr part. Physical and chemical properties molecular formula c6h5ch3. In case of skin contact wash off with soap and plenty of water. Osha no component of this product present at levels greater than or equal to 0. When heated above the flash point, this material emits flammable vapors which, when mixed with air, can burn or be explosive. Other international regulations the information provided on this safety data sheet is correct to the best of our knowledge, information and belief at the date relates only to the specific material designated and may not be valid for such material used in combination with any other. Therefore ethylaluminum compounds are usually used unless the nucleophilicity of the alkyl group is a problem. Product identifier product name toluene product number toen reach registration number 012119471051xxxx cas number 108883 eu index number 601021003 ec number 2036259 1. March 1, 20 the dow chemical company page 3 of 7 sampling, testing, or other procedures. The user must determine suitability of this information for his. As a global supplier of aluminum alkyls, we have an intense focus on safety and an active product stewardship program involving our customers.
Benzene methyl, methacide, toluole, methyl benzol, toluene. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect personnel attempting to stop a leak. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Dichloromethane material safety data sheet cas no 75092. Ethylaluminium sesquichloride, also called easc, is an industrially important organoaluminium compound used primarily as a precursor to triethylaluminium and as a catalyst component in zieglernatta type systems for olefin and diene polymerizations.
Show this safety data sheet to the doctor in attendance. Ethylaluminum dichloride c2h5alcl2 cid 11237 structure, chemical names, physical. Chlorohydridotristriphenylphosphine rutheniumii toluene adduct. Aa59107 aa59107 toluene technical page 3 of 6 explosion hazard. Material safety data sheet ethylene dichloride msds name. September 8, 2009 information in this msds is from available published sources and is believed to be accurate. Relevant identified uses of the substance or mixture and uses advised against 1. The solvent, toluene, is mildly toxic by inhalation. Dispose of contents and container in accordance with all local, regional, national and international regulations.
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